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branches is ascribed to the fact that it is formed through a 6-membered transition state (consisting of the ve carbons and the hydrogen being abstracted). Ethyl branches arise from radical XXIVc undergoing a second intramolecular transfer reaction after the addition of one ethylene molecule prior to further propagation, leading to 1,3-diethyl (Eq. 3-130a) and 2ethylhexyl branches (Eq. 3-130b).

Successful merchants had to become connoisseurs of bank notes, accepting only the best at par Although the new country freely copied many English commercial and financial institutions and drew on Europe s centuries of experience in credit forms and banking techniques, it accepted only briefly the power and guidance of a central bank The first Bank of the United States, 1791 1811, and the second Bank of the United States, 1817 1836, were deeply involved in politics, just as was the Bank of England in its youth The Bank of England s friends, however, remained in power long enough to permit it to become a dominant factor in finance and an invaluable aid to any government The friends of the two Banks of the United States held insufficient tenure Finance itself was less important and less respected in the new nation, and centralized power of all sorts was suspect.

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CH3 CH2 (3-128c)

(3-129)

Open It Up!

Even at the present time there are not one but dozens of American banking systems The bankers of London were also merchants They insisted that their prime short bills must always have a market at a price and they always had one, thanks to the Bank of England In the United States no one.

CH2CH3 CH2CHCH2CH CH2CH2CH2CH3 2-Ethylhexyl branch XXVIb (3-130b)

Short branching has also been veri ed in poly(vinyl acetate), poly(vinyl chloride), and various polyacrylates. Branching in poly(vinyl acetate) and polyacrylates involve the intramolecular backbiting mechanism as in polyethylene [Adelman and Ferguson, 1975; Heatley

et al., 2001; Morishima and Nozakura, 1976; Nozakura et al., 1976]. Short branching in poly(vinyl chloride) is a more complex process [Hjertberg and Sorvik, 1983; Starnes, 1985; Starnes et al., 1983, 1992, 1995]. 2-chloroethyl and 2,4-dichloro-n-butyl branches are formed via the backbiting route, with the latter more abundant ($1 per 1000 monomer units) than the former. However, the most abundant branches are chloromethyl groups up to 4 6 per 1000 monomer units. Chloromethyl groups occur when radical XIX (formed via Eq. 3-114) undergoes propagation:

undertook this responsibility for the community as a whole until the twentieth century The decentralized nineteenth-century money markets lacked a common pool of reserve funds, an instrument of national monetary policy, and a lender of last resort In consequence there were weird fluctuations in the rates on short-term market paper, far wider than any reported from European centers As late as 1899 call money on the New York Stock Exchange ranged from a low of 1% per annum to a high of 186% per annum In contrast, in the same year the yields of prime longterm American corporate and municipal bond averages ranged from 307% low to 323% high The financial vicissitudes of the Civil War and the aroused spirit of nationalism led directly to the organization of the National Banking System A uniform circulation was desired.

3-131

Simple enough, until you get all the screws out and see that it s still not about to open. Why For some mysterious reason, all along the front edge of the case there exists an interlock that must be pulled apart. Keeping the halves of the case flat to each other, begin at one end to pull the case halves apart. After a bad-news sound of plastic ripping, the halves do come apart without damage and the circuit is finally exposed.

Long branches in PVC, up to about one branch per 2000 monomer units, arise from hydrogen abstraction at the CHCl group in the polymer chain. 3-6e Catalytic Chain Transfer

In 1862, 1496 banks were circulating notes under the laws of twenty-nine states, all different Some states chartered many kinds of banks Seven thousand different kinds of notes circulated, aside from counterfeits There were 5500 varieties of altered and fraudulent notes (489) When the issue of United States notes in 1862 was followed by a decline in the specie value of all paper money, the blame was placed on bank notes rather than on government notes It was argued that a currency secured solely by government bonds would improve public credit and encourage national union In 1863 an act was approved to provide a national currency secured by a pledge of United States securities Nationally chartered banks, upon depositing United States bonds with the Treasury, could receive from it and issue notes up to 90% of the market or par value of the bonds, whichever was lower.

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