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Many polymers are crosslinked by compounding with a peroxide such as dicumyl peroxide or di-t-butyl peroxide and then heating the mixture [Alliger and Sjothun, 1964; Coran, 1978; Emami et al., 2002; Keller, 1988; Peacock, 1987; Ratzsch et al., 2002; Yamazaki and Seguchi, 2000]. Peroxide crosslinking of diene polymers works with all except butyl rubber, which undergoes chain scission. The crosslinks formed via peroxides are more thermally stable than those formed via sulfur vulcanization. However, peroxide crosslinking is not economically competitive with sulfur crosslinking because of the high cost of peroxides. Peroxide crosslinking is primarily used for those polymers that cannot be easily crosslinked by sulfur, such as polyethylene and other polyole ns, ethylene propene (no diene) rubbers (EPM), and polysiloxanes. Crosslinking of polyethylene increases its strength properties and extends the upper temperature limit at which this plastic can be used. Uses include electrical wire and cable insulation, pipe, and hose. For EPM and polysiloxanes, crosslinking is essential to their use as elastomers. vb.net merge pdf files Merge Pdf Files and Add Bookmarks to It (Using iTextSharp)-VBForums
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