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calculated by Eq (211), U = H - P V In this way tables of thermodynamic properties are compiled over the entire useful range of conditions The most widely used such tabulation is for H 2 0 and is known as the steam tables1 The enthalpy may be taken as zero for some other state than liquid at 27315 K (0 C) The choice is arbitrary The equations of thermodynamics, such as Eqs (232) and (233), apply to changes of state, for which the enthalpy differences are independent of the location of the zero point However, once an arbitrary zero point is selected for the enthalpy, an arbitrary choice cannot be made for the internal energy, for values of internal energy are then calculable from the enthalpy by Eq (211)

lostearn tables are given in App F Tables for various other substances are found in the literature A discussion of compilations of thermodynamic properties appears in Chap 6

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a stirrer, which is made to turn by gravity acting on a weight of mass 35 kg The weight falls slowly through a distance of 5 m in driving the stirrer Assuming that all work done on the weight is transferred to the water and that the local acceleration of gravity is 98 m sp2,determine: (a) The amount of work done on the water (6) The internal-energy change of the water ( c ) The final temperature of the water, for which C p = 418 kJ kg-' 'C-' ( d ) The amount of heat that must be removed from the water to return it to its initial temperature (e) The total energy change of the universe because of (1) the process of lowering the weight, (2) the process of cooling the water back to its initial temperature, and (3) both processes together

Private Sub MyApplication_Startup(ByVal sender As Object, _ ByVal e As Microsoft.VisualBasic.ApplicationServices. _ StartupEventArgs) Handles Me.Startup ' ----- Take a three-second nap. System.Threading.Thread.Sleep(3000) End Sub

22 Rework Prob 21 for an insulated container that changes in temperature along with the water and has a heat capacity equivalent to 5 kg of water Work the problem with: (a) The water and container as the system; (b) The water alone as the system 23 An egg, initially at rest, is dropped onto a concrete surface and breaks With the egg treated as the system, ( a ) What is the sign of W (b) What is the sign of A Ep (c) What is AEK ( d ) What is AU' ( e ) What is the sign of Q In modeling this process, assume the passage of sufficient time for the broken egg to return to its initial temperature What is the origin of the heat transfer of part (e) 24 An electric motor under steady load draws 97 amperes at 110 volts, delivering 093 kW of mechanical energy What is the rate of heat transfer from the motor, in kW

25 One mole of gas in a closed system undergoes a four-step thermodynamic cycle Use the data given in the following table to determine numerical values for the missing quantities, ie, "fill in the blanks"

Now run the program, and you will see the splash screen stick around for about three seconds (3,000 milliseconds). As gratifying as it is to see the splash screen for that long, there s a good chance that the actual database and application initialization code will take much less than three seconds. I mean, we re talking about SQL Server here. It s supposed to be blazing fast. So, it s clear that we still need to delay the removal of the splash screen. The My. Application object just happens to include the very property we need to enforce a delay. The MinimumSplashScreenDisplayTime property indicates the minimum number of milliseconds that the splash screen must be displayed. The bad part is that you have to assign it in a really strange place, at least when compared to how much Visual Basic programming we ve learned so far. Delete all the code that you added from snippet 1, which would be the entire MyApplication_Startup method. Then fill in that empty space with the following code.

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Protected Overrides Function OnInitialize _ (ByVal commandLineArgs As System.Collections. _ ObjectModel.ReadOnlyCollection(Of String)) As Boolean ' ----- Display the splash form for at least 3 seconds. My.Application.MinimumSplashScreenDisplayTime = 3000 Return MyBase.OnInitialize(commandLineArgs) End Function

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