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26 Comment on the feasibility of cooling your kitchen in the summer by opening the door to the electrically powered refrigerator 27 A renowned laboratory reports quadruple-point coordinates of 102 Mbar and 29725 K (241 C) for four-phase equilibrium of allotropic solid forms of the exotic chemical 8-miasmone Evaluate the claim 28 A closed, nonreactive system contains species 1 and 2 in vaporlliquid equilibrium Species 2 is a very light gas, essentially insoluble in the liquid phase The vapor phase contains both species 1 and 2 Some additional moles of species 2 are added to the system, which is then restored to its initial T and P As a result of the process, does the total number of moles of liquid increase, decrease, or remain unchanged 29 A system comprised of chloroform, 1,4-dioxane, and ethanol exists as a two-phase vaporlliquid system at 32315 K (50 C) and 55 kPa It is found, after the addition of some pure ethanol, that the system can be returned to two-phase equilibrium at the initial T and P In what respect has the system changed, and in what respect has it not changed 210 For the system described in Pb 29: (a) How many phase-rule variables in addition to T and P must be chosen so as to fix the compositions of both phases (b) If the temperature and pressure are to remain the same, can the overall composition of the system be changed (by adding or removing material) without affecting the compositions of the liquid and vapor phases 211 A tank containing 20 kg of water at 29315 K (20 C) is fitted with a stirrer that delivers work to the water at the rate of 025 kW How long does it take for the temperature of the water to rise to 30315 K (30 C) if no heat is lost from the water For water, C p = 418 k~ kg-' "c-' 212 Heat in the amount of 75 kJ is added to a closed system while its internal energy decreases by 12 kJ How much energy is transferred as work For a process causing the same change of state but for which the work is zero, how much heat is transferred 213 A steel casting weighing 2 kg has an initial temperature of 77315 K (500 C); 40 kg of water initially at 29815 K (25 C) is contained in a perfectly insulated steel tank.

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That code block contains a lot of things we just haven t talked about yet, and won t talk about for a few more chapters. Suffice it to say that the OnInitialize method is one of the first things that happens in the lifetime of the program, and that is the place where MinimumSplashScreenDisplayTime must be assigned.

A McQuarrie, Statistical Mechanics, pp 81-82, Harper & Row, New York, 1976

152 152

The equations of statistical mechanics are derived by application of Eq (541) to a large number of macroscopicallyidentical systems (an ensemble) in all of their many allowed quantum states The entropy S as given by Eq (542) is then a statistical average value for the ensemble" Ultimately, the result is an equation for the entropy:

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The last thing to do for the splash screen is to include some code that displays the version number. We already did this for the About form back in 5, so we ll just add similar code to the Splash form s Load event. We ll update the copyright message, too. Open the source code for the Splash form and add the following code.

where 2 is the partition function, given by Eq (1613), and U is the internal energy as given by Eq (1614) For an ideal gas, combination of Eqs (1616) and (1617) with Eq (1619) yields:

SmartMedia CompactFlash Memory Stick Secure Digital (SD) Floppy Disk Choosing a Memory Card Format Transferring Images to the PC Transferring Images with a Serial Cable Transferring Images with a USB Port Transfer Shortcuts: Using Memory Adapters Caring for Your Memory Cards CHAPTER 9 153 154 154 155 155 156 158 159 162 164 166

According to Stirling's formula In N A ! = NA In NA - NA; also kNA = R Making these substitutions gives:

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Private Sub Splash_Load(ByVal sender As Object, _ ByVal e As System.EventArgs) Handles Me.Load ' ----- Update the version number. With My.Application.Info.Version ProgramVersion.Text = "Version " & .Major & "." & _ .Minor & " Revision " & .Revision End With ProgramCopyright.Text = My.Application.Info.Copyright End Sub

Upon rearrangement, this may be written:

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